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Here, we examine the advances in EDLC research to achieve a high operating voltage window along with high energy densities, covering from materials and electrolytes to long-term device perspectives for next-generation supercapacitor-based ESSs. 1. Introduction. The global transition to sustainable energy systems and the growing demand for high-efficiency electrical infrastructure necessitate groundbreaking innovations across materials, devices, and system-level engineering. This Reserach Topic focuses on cutting-edge advancements in energy storage. . This review offers a critical and exhaustive examination of the current state and innovative advances in high-voltage Li, Na, K, and Zn aqueous rechargeable batteries, an area poised for significant technological breakthroughs in energy storage systems. The practical issues that have traditionally. . Solar photovoltaic (SPV) materials and systems have increased effectiveness, affordability, and energy storage in recent years. Recent technological advances make solar photovoltaic energy generation and storage sustainable. The intermittent nature of solar energy limits its use, making energy. . ents, energy production, and environmental impact using a dynamic optimization model. Our findings show that increasing investment in renewables supports both en-ergy generatio and ecological sustainability, with the optimal path depending on policy priorities. Our analysis demonstrates that the. . Therefore, there is a surging demand for developing high-performance energy storage systems (ESSs) to effectively store the energy during the peak time and use the energy during the trough period. To this end, supercapacitors hold great promise as short-term ESSs for rapid power recovery or.