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The perfluorosulfonic acid ion exchange membrane has narrow molecular weight distribution, controllable molecular weight, larger crystalline area and crystallinity, good ion selectivity, and excellent mechanical properties, and can be better used in flow batteries.. The perfluorosulfonic acid ion exchange membrane has narrow molecular weight distribution, controllable molecular weight, larger crystalline area and crystallinity, good ion selectivity, and excellent mechanical properties, and can be better used in flow batteries.. A proton exchange membrane (PEM) is a crucial component for the effective and stable operation of energy conversion and storage devices, such as fuel cells, water electrolyzers, and redox flow batteries. However, perfluorinated sulfonic acid (PFSA) membranes—the most widely used PEM—have ultimate. . Perfluorosulfonic acid (PFSA) membrane, or perfluorosulfonic acid ion exchange membrane (PFSIEM), is a perfluoropolymer membrane with a polytetrafluoroethylene structure as the backbone and an alkenyl ether structure with sulfonate groups at the end as side chains. It has good chemical stability. . The microstructure of perfluorinated sulfonic acid proton-exchange membranes such as Nafion significantly affects their transport properties and performance in a vanadium redox-flow battery (VRB). In this work, Nafion membranes with various equivalent weights ranging from 1000 to 1500 are prepared. . This study systematically investigated the physicochemical properties and proton exchange membrane fuel cell (PEMFC) performance of perfluorosulfonic acid (PFSA) membranes with different thicknesses, which were prepared based on the resins produced by Dongyue (China) in comparison with commercial. . Membrane materials based on perfluorosulfonic acid polymers (PFSA) possess a set of characteristics necessary for their practical application: high ionic conductivity and selectivity and good chemical stability, strength, and elasticity. This review addresses the microstructure of PFSA membranes. . Abstract: Polymer ion-exchange membranes are featured in a variety of modern technologies includ-ing separation, concentration and purification of gases and liquids, chemical and electrochemical synthesis, and hydrogen power generation. In addition to transport properties, the strength.