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The (Zn–Br2) was the original flow battery. John Doyle file patent on September 29, 1879. Zn-Br2 batteries have relatively high specific energy, and were demonstrated in electric cars in the 1970s. Walther Kangro, an Estonian chemist working in Germany in the 1950s, was the first to demonstrate flow batteries based on dissolved transition metal ions: Ti. Flow batteries have certain technical advantages over conventional rechargeable batteries with solid electroactive materials, such as independent scaling of power (determined by the size of the stack) and of energy (determined by the size of the tanks), long cycle and calendar life . . Flow batteries have certain technical advantages over conventional rechargeable batteries with solid electroactive materials, such as independent scaling of power (determined by the size of the stack) and of energy (determined by the size of the tanks), long cycle and calendar life . . Bromine-based redox flow batteries (Br-FBs) have emerged as a technology for large-scale energy storage, offering notable advantages such as high energy density, a broad electrochemical potential window, cost-effectiveness, and extended cycle life. This review explores the most extensively studied. . A new advance in bromine-based flow batteries could remove one of the biggest obstacles to long-lasting, affordable energy storage. Scientists developed a way to chemically capture corrosive bromine during battery operation, keeping its concentration extremely low while boosting energy density. . A new twist on bromine-based flow batteries could make large-scale energy storage cheaper, safer, and far longer-lasting. Bromine-based flow batteries store and release energy through a chemical reaction involving bromide ions and elemental bromine. This approach offers several advantages. . However, during charging, bromine readily forms a highly corrosive species (Br 2) that attacks battery components, shortening lifespan and increasing costs.
